Starrk, Barragan and Harribel Are Not the Final Wall
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Episodes 273–286
The top Espada are powerful enough to occupy Soul Society's strongest fighters, but defeating them does not solve the war. Barragan dies cursing the master he served, Starrk falls after fighting with a loneliness that mirrors his creation, and Aizen cuts Harribel down himself once he decides the Espada have failed him. The hierarchy Aizen built was always disposable to Aizen.
The Fake Karakura Town Lets the Captains Fight Without Sacrificing the Real One
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Episodes 203 & 215 onward · Decisive Battle
Aizen needs Karakura Town for his larger plan, so Soul Society replaces the real town with a replica and moves the population out of the battlefield. That preparation turns the conflict into the series' largest captain-level war: Espada, lieutenants, Visored and captains collide while Aizen waits behind the force meant to stop him.
Gin Betrays Aizen After Years at His Side
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Episodes 297–308 · Kamishini no Yari
Gin's loyalty was always harder to read than Aizen's confidence suggested. When he finally turns on Aizen, the move is tied to Rangiku and to knowledge of Kyōka Suigetsu's weakness that he spent years positioning himself to exploit. The attempt fails because the Hōgyoku has already made Aizen harder to kill than Gin calculated, but the betrayal finally explains why Gin stayed beside him for so long.
Final Getsuga Tenshō Ends the Aizen Fight and Ichigo's Shinigami Power
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Episodes 306–310
Dangai training gives Ichigo the answer to Aizen, but not for free. Mugetsu overwhelms the evolved Aizen at the price of Ichigo's own Shinigami power. Urahara's seal finishes the job once the Hōgyoku stops carrying Aizen forward. The arc ends with the hero alive, his friends safe, and the power that defined the series draining away from him.